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Nonlinear dielectric spectroscopy in a fragile plastic crystal

机译:脆性塑料晶体中的非线性介电谱

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摘要

In this work we provide a thorough examination of the nonlinear dielectricproperties of a succinonitrile-glutaronitrile mixture, representing one of therare example of a plastic crystal with fragile glassy dynamics. The detectedalteration of the complex dielectric permittivity under high fields can beexplained considering the heterogeneous nature of glassy dynamics and afield-induced variation of entropy. While the first mechanism was also found instructural glass formers, the latter effect seems to be typical for plasticcrystals. Morover, the third harmonic component of the dielectricsusceptibility is reported, revealing a spectral shape as predicted forcooperative molecular dynamics. In accord with the fragile nature of the glasstransition in this plastic crystal, we deduce a relatively strong temperaturedependence of the number of correlated molecules, in contrast to the muchweaker temperature dependence in plastic-crystalline cyclo-octanol, whose glasstransition is of strong nature.
机译:在这项工作中,我们提供了对丁二腈-戊二腈混合物的非线性介电性能的全面检查,代表了具有脆弱玻璃态动力学的塑料晶体的一个罕见例子。考虑到玻璃态动力学的异质性和场感应的熵变化,可以解释在高场下检测到的复介电常数的变化。虽然第一个机理也被发现是教学玻璃的形成者,但后者的作用似乎是塑料晶体的典型现象。据报道,Morover是介电敏感性的三次谐波分量,揭示了光谱形状,正如预测的合作分子动力学一样。与这种塑料晶体中玻璃化转变的脆弱性相一致,我们推断出相关分子数量的温度依赖性相对较强,而塑料化环辛醇的玻璃化转变具有很强的性质,而温度依赖性则弱得多。

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